Weathering is the process of breaking down rocks by mechanical and chemical processes into smaller pieces. Weathering occurs in situ with no visible movement and thus should differ from erosion that, it involves the movement of rocks and minerals by agents such as water, ice, wind and gravity. The weathering of the rocks might be by physical disintegration, and/or chemical decomposition.
1) Physical/Mechanical Weathering
Physical weathering involves the breakdown of rocks and soils through direct contact with atmospheric conditions such as heat, water, ice and pressure, without any change in chemical condition. The soil formed due to physical weathering will be cohesionless (sand and gravel). It reduces the size of the parent rock material, without any change in the original composition of the parent rock. Mechanical weathering may be caused by the expansion and contraction of rocks from the continuous gain and loss of heat, which results in ultimate disintegration. Frequently, water seeps into the pores and existing cracks in rocks. As the temperature drops, the water freezes and expands. The pressure exerted by ice because of volume expansion is strong enough to break down even large rocks. Other physical agents that help disintegrate rocks are glacier ice, wind, the running water of streams and rivers, and ocean waves.
The main processes involved are exfoliation, unloading, erosion, freezing, and thawing. The principal cause is climatic change. In exfoliation, the outer shell separates from the main rock. Heavy rain and wind cause erosion of the rock surface. Adverse temperature changes produce fragments due to different thermal coefficients of rock minerals.
Temperature changes of sufficient amplitude and frequency bring about changes in the volume of the rocks in the superficial layers of the earth's crust in terms of expansion and contraction. Such a volume change sets up tensile and shear stresses in the rock ultimately leading to the fracture of even large rocks. This type of rock weathering takes place in a very significant manner in arid climates where free, extreme atmospheric radiation brings about considerable variation in temperature at sunrise and sunset. Erosion by wind and rain is a very important factor and a continuing event. Cracking forces by growing plants and roots in voids and crevasses of rock can force fragments apart.
In summary, the physical agencies causing mechanical weathering of rocks are;
- Daily and seasonal temperature changes.
- Flowing water, glaciers and wind, which produce impact and abrasive action on rock.
- Splitting action of ice.
- Growth of roots of plants in rock fissures and to a minor degree burrowing activities of small animals like earthworms.
2) Chemical Weathering
Chemical weathering (decomposition) can transform hard rock minerals into soft, easily erodible matter. The principal types of decomposition are hydration, oxidation, carbonation, desalination and leaching. In chemical weathering, the original rock minerals are transformed into new minerals by chemical reaction. Oxygen and carbon dioxide which are always present in the air readily combine with the elements of rock in the presence of water. Water and carbon dioxide from the atmosphere form carbonic acid, which reacts with the existing rock minerals to form new minerals and soluble salts. Soluble salts present in the groundwater and organic acids formed from decayed organic matter also cause chemical weathering.
Chemical weathering changes the composition of rocks by decomposing the parent minerals, transforming them into new compounds such as clay silica particles, carbonates and iron oxides. An example of the chemical weathering of orthoclase to form clay minerals, silica, and soluble potassium carbonate follows:
H2O + CO2 → H2CO3 → H+
+
(HCO3 ) –
2K(AlSi3O8) + 2H+ + H2O → 2K+ + 4SiO2
+ Al2Si2O5(OH)4
H2CO3 - Carbonic
acid
2K(AlSi3O8) -
Orthoclase
SiO2 - Silica
Al2Si2O5(OH)4 - Kaolinite (Clay mineral)
Most of the potassium ions released are carried away in solution as potassium carbonate is taken up by plants. The chemical weathering of plagioclase feldspars is similar to that of orthoclase in that it produces clay minerals, silica and different soluble salts. Ferromagnesian minerals also form the decomposition products of clay minerals, silica and soluble salts. The iron and magnesium in ferromagnesian minerals result in other products such as hematite and limonite. Quartz is highly resistant to weathering and only slightly soluble in water.
The effects of weathering and transportation mainly determine the basic nature of the soil (size, shape, composition and distribution of the particles). The environment into which deposition takes place, and the subsequent geological events that take place there, determine the state of the soil (density, moisture content) and the structure or fabric of the soil (bedding, stratification, occurrence of joints or fissures). The decomposition of rock is the result of the following reactions.
1) Oxidation
Within the weathering environment, oxidation of a variety of metals occurs. The most commonly observed is the oxidation of Fe2+ (iron) and combination with oxygen and water to form Fe3+ hydroxides and oxides such as goethite, limonite and hematite. This gives the affected rocks a reddish-brown colour on the surface which crumbles easily and weakens the rock. This process is better known as ‘rusting’.
2) Carbonation
Carbonation of rock material is caused by carbon dioxide in the presence of water. Limestone is very much affected by carbonation.
3) Hydration
Mineral hydration is a form of chemical weathering that involves the rigid attachment of H+ and OH- ions to the atoms and molecules of a mineral. When rock minerals take up water, the increased volume creates physical stresses within the rock. For example iron oxides are converted to iron hydroxides and the hydration of anhydrite forms gypsum. Another example of hydration is the chemical decomposition of mineral feldspar in granite to form kaolite.
4) Leaching
Leaching is the process in which percolating water washes out water-soluble salts from the soil. Soil produced by chemical weathering of rocks will be cohesive (silt and clay).
Transportation of Weathering Products
The products of weathering may stay in the same place or may be moved to other places by ice, water, wind and gravity. In water or air, the grains become sub-rounded or rounded and the grain sizes get sorted so as to form poorly graded deposits. In moving ice, grinding and crushing occurs, size distribution becomes wider forming well graded deposits. In running water, soil can be transported in the form of suspended particles, or by rolling and sliding along the bottom. Coarser particles settle when a decrease in velocity occurs, whereas finer particles are deposited further downstream. In still water, horizontal layers of successive sediments are formed, which may change with time, even seasonally or daily. Wind can erode, transport and deposit fine grained soils. Wind-blown soil is generally uniformly graded. A glacier moves slowly but scours the bedrock surface over which it passes. Gravity transports materials along slopes without causing much alteration.
The soils formed by the weathered products at their place of origin are called residual soils. An important characteristic of residual soil is the gradation of particle size. Fine-grained soil is found at the surface, and the grain size increases with depth. At greater depths, angular rock fragments may also be found. The transported soils may be classified into several groups, depending on their mode of transportation and deposition.
1. Glacial soils - formed by transportation and deposition of glaciers
2. Alluvial soils - transported by running water and deposited along streams
3. Lacustrine soils - formed by deposition in quiet lakes
4. Marine soils - formed by deposition in the seas
5. Aeolian soils - transported and deposited by wind
6. Colluvial soils - formed by movement of soil from its original place by gravity, such as during landslides